Question 1

Explain the difference in boiling points between H2S and H2O.

Question 2

Draw the shapes of:

SCl2, SO2Cl2, SOCl2, SOF4

Question 3

Give a preparation for:

H2S, SO2, SO3, SO32-, SO42-, S2O32-

Question 4

Draw S2O32- and explani why the 2 S atoms in this compound have a different oxidation state.

Question 5

2.75g of white powder was known to consist of a mixture of Na2SO4, Na2CO3, and Na2SO3. On the addition of aqueous BaCl2 followed by addition of an acid, 1.35g of white precipitate were collected. It was also noted that 130cm3 of CO2 were also produced from the reactions.

Find the percentage by mass of all the compounds in the mixture.

Question 6

Sulfur oxides are a big source of pollution. Give 3 ways how to reduce the Sulfur oxides emissions from transport.

Question 7

In each of the following reactions, balance the reaction and identify the oxidant and the reductant.

i) I_2+S_2O_3^2^-\rightarrow S_4O_6^2^-+I^-

ii) H_2S+Cr_2O_7^2^-\rightarrow Cr^3^++H_2O+S

iii) Zn+SO_4^2^-+H^+\rightarrow Zn^2^++SO_2+H_2O

Question 8

The following 2 chemical reactions illustrate 2 properties for H2SO4.

C_1_2H_2_2O_1_1\xrightarrow[]{conc\: \: H_2SO_4}12C+11H_2O

C+2H_2SO_4\rightarrow CO_2+SO_2+2H_2O

What properties are shown in the above 2 reactions?

Question 9

H2SO4 has a number of properties. Discuss 3 more properties of H2SO4 not mentioned in question 8.

Question 10

A compound containing S, O and Cl reacts with water to produce H2SO4 and HCl.

6.75g of compound was reacted in water in the solution was made up to 1000cm3.

50cm3 of this solution reacted with BaCl2 and 0.5835g of precipitate was formed.

50cm3 of this solution required 20cm3 of 0.5M NaOH for complete neutralisation.

When 0.5g of compound was vaporised it occupied 112cm3 at 100oC and 1atm.

What is the molecular formula?