Moles III – Empirical Formulae

Question 1

What is the empirical formula of a compound containing 60.0% sulfur and 40.0% oxygen by mass?

Question 2

A compound is found to contain 23.3% magnesium, 30.7% sulfur, and 46.0% oxygen. What is the empirical formula of this compound?

Question 3

What is the empirical formula for a compound containing 38.8% carbon, 16.2% hydrogen, and 45.1% nitrogen?

Question 4

A sample of an oxide of nitrogen is found to contain 30.4% nitrogen. What is its empirical formula?

Question 5

A sample of an oxide of arsenic is found to contain 75.74% arsenic. What is its empirical formula?

Question 6

What is the empirical formula for a compound containing 26.57% potassium, 35.36% chromium, and 38.07% oxygen?

Question 7

A compound with an empirical formula of C2OH4 and a molar mass of 88. What is the molecular formula of this compound?

Question 8

A compound with an empirical formula of C4H4O and a molar mass of 136. What is the molecular formula of this compound?

Question 9

A compound that is 9.4% C, 14.9% F, 62.7% Br, and 6.3% Oxygen has a molar mass of 237.8. What is the molecular formula of this compound?

 

Question 10

A carbohydrate on analysis gave the following composition: carbon = 40.0%; hydrogen = 6.71%, and oxygen made up the rest. Calculate the molecular formula of this organic compound which has a molecular mass of 181.

Question 11

Nicotine is mainly responsible for the addictive nature of cigarettes. A typical cigarette contains 12.33 mg C, 1.45 mg H, & 2.87 mg N. If the molar mass of nicotine is 162 g/mol, what is the molecular formula of nicotine?

Question 12

An unknown compound was found to have a percent composition as follows: 47.0 % potassium, 14.5 % carbon, and 38.5 % oxygen. What is its empirical formula? If the true molar mass of the compound is 166.22 g/mol, what is its molecular formula?

Question 13

NutraSweet is 57.14% C, 6.16% H, 9.52% N, and 27.18% O. Calculate the empirical formula of NutraSweet and find the molecular formula. (The molar mass of NutraSweet is 294.30 g/mol)

Question 14

What’s the empirical formula of a molecule containing 65.5% carbon, 5.5% hydrogen, and 29% Oxygen? If the molar mass is 110 g/mol, what is the molecular formula?

Question 15

Caffeine has the following percent composition: 49.47% C, 5.201% H, 28.84% N, and 16.48% O If the molecular mass of caffeine is 194.2 amu, what is it’s molecular formula?

 

Question 16

The combustion of 3.42 g of a compound is known to contain only nitrogen and hydrogen gave 9.82 g of NO2 and 3.85 g of water. Determine the empirical formula of this compound.

Question 17

A 2.52 g sample of a compound containing carbon, hydrogen, nitrogen, oxygen, and sulfur was burned in excess oxygen gas to yield 4.36 grams of CO2 and 0.892 grams of H2O as the only carbon and hydrogen products respectively. Another sample of the same compound of mass 4.14 g yielded 2.60 g of SO3 as the only sulfur containing product. A third sample of mass 5.66 g was burned under different conditions to yield 2.80 g of HNO3 as the only nitrogen containing product. Determine the empirical formula of the compound.

 

Question 18

A compound with a known molecular weight (146.99 g/mol) that contains only C, H, and Cl was studied by combustion analysis. When a 0.367 g sample was combusted, 0.659 g of CO2 and 0.0892 g of H2O formed. What are the empirical and molecular formulas?

 

Question 19

A 6.20-g sample of an unknown compound containing only C, H, and O combusts in an oxygen rich environment. When the products have cooled to 20.0 °C at 1 bar, there are 8.09 L of CO2 and 3.99 mL of H2O. The density of water at 20.0 °C is 0.998 g/mL.