Steps on how to write an ionic equation

  1. Write down the normal balanced equation

NaOH + HCl → NaCl + H2O

  1. Write down the equation substituting the ionic compounds into their respective ions. covalent compounds which are partially ionised are written as the two ions formed while non-ionisable covalent molecules are written down as compounds.

Na+ OH + H+ Cl → Na+Cl + H2O

  1. Omit the spectator ions. These are the ions that remain unchanged on both sides of the equation.

Na+OH + H+ Cl Na+Cl + H2O

  1. Write down the ionic equation. It must be noted that the charges on both sides should be equal. If no charge is present on the LHS then no charge should be present on the RHS

OH(aq) + H+(aq) → H2O(l)

Acid base reaction

H2SO4 + CuO → CuSO4 + H2O

2H+SO42 + Cu2+ O2-Cu2+SO42- + H2O

2H+(aq) + O2-(aq) → H2O(l)

3HNO3 + Al(OH)3 → Al(NO3)3 + 3H2O

3H+3NO3 + Al3+ 3OHAl3+3NO3 + 3H2O

H+(aq) + OH(aq) → H2O(l)

Acid metal reaction

Zn + 2HCl → ZnCl2 + H2

Zn + H+Cl → Zn2+Cl + H2

Zn(s) + 2H(aq)à→ Zn2+(aq) + H2(g)

Mg + H2SO4 → MgSO4 + H2

Mg + H+SO42- → Mg2+SO42- + H2

Mg(s) + 2H+(aq) → Mg2+(aq) + H2(g)

Acid Carbonate/Hydrogen Carbonate reaction

CaCO3 + 2HCl → CaCl2 + CO2 + H2O

Ca2+ CO32- + H+Cl Ca2+Cl + CO2 + H2O

2H+(aq)+ CO32-(aq)→ CO2(g) + H2O(l)

2NaHCO3 + H2SO4 → Na2SO4 + CO2 + H2O

Na+ HCO3 + 2H+SO42 Na+SO42- + CO2 + H2O

2H+(aq) + HCO­3(aq)→ CO2(g) + H2O(l)

Metal Displacement

Mg + CuSO4 → MgSO4 + Cu

Mg + Cu2+ SO42-  → Mg2+SO42- + Cu

Mg(s) + Cu2+(aq) → Mg2+(aq) + Cu(s)

Al + Zn(NO3)2 → Al(NO3)3 + Zn

Al + Zn2+NO3 → Al3+NO3 + Zn

2Al(s) + 3Zn2+(aq) → 2Al3+(aq) + 3Zn(s)

Non metal displacement

2KI + Cl2 → 2KCl + I2

K+ I + Cl2 K+ Cl + I2

2I(aq) + Cl2(g) → 2Cl(aq) + I2(g)

NaBr + F2 → NaF + Br2

Na+ Br + F2Na+ F + Br2

2Br(aq) + F2(g) → 2F(aq) + Br2(g)

Ionic Precipitation

Pb(NO3)2 + NaI → PbI2 + NaNO3

Pb2+NO3 + Na+ I → Pb2+I + Na+NO3

Pb2+(aq) + I(aq) → PbI2(s)

CaCl2 + Na2CO3 → CaCO3 + 2NaCl

Ca2+Cl + Na+ CO32- →Ca2+CO32- + Na+Cl

Ca2+(aq) + CO32-(aq) → CaCO3(s)

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